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In a series of donor-acceptor adducts of amines to triorganylboroxines (Tables 1,2) it has been shown by 1H and 11B NMR spectroscopy that in solution the amine undergoes a temperature dependent fluctuation between the boron atoms of the boroxine ring.In the solid state, as determined by X-ray structural analysis of two selected 3:2 an 1:2 adducts (3 and 6) (boron-nitrogen ratios of 1:1 and 3:1, respectively), only one boron atom of each boroxine ring is involved in adduct formation.
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Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis