Safety of 1,5-Dibromopentane. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: 1,5-Dibromopentane, is researched, Molecular C5H10Br2, CAS is 111-24-0, about Crystal structure and halogen-hydrogen bonding of a Delepine reaction intermediate. Author is Mulrooney, David Z. T.; Muller-Bunz, Helge; Keene, Tony D..
The reaction of 1,5-dibromopentane with urotropine results in crystals of the title mol. salt, 5-bromourotropinium bromide [systematic name: 1-(5-bromopentyl)-3,5,7-triaza-1-azoniatricyclo[3.3.1.13,7]decane bromide], C11H22BrN4+·Br- (1), crystallizing in space group P21/n. The packing in compound 1 is directed mainly by H···H van der Waals interactions and C-H···Br hydrogen bonds, as revealed by Hirshfeld surface anal. Comparison with literature examples of alkylurotropinium halides shows that the interactions in 1 are consistent with those in other bromides and simple chloride and iodide species.
In addition to the literature in the link below, there is a lot of literature about this compound(1,5-Dibromopentane)Safety of 1,5-Dibromopentane, illustrating the importance and wide applicability of this compound(111-24-0).
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis