Application In Synthesis of 1,2-Bis(diphenylphosphino)ethane. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: 1,2-Bis(diphenylphosphino)ethane, is researched, Molecular C26H24P2, CAS is 1663-45-2, about Nano cadmium(II)-benzyl benzothiazol-2-ylcarbamodithioate complexes: Synthesis, characterization, anti-cancer and antibacterial studies.
Benzyl benzothiazol-2-ylcarbamodithioate (BBCT) was used as a ligand for the synthesis of [Cd(BBCT)(PPh3)Cl]Cl (1), [Cd2(BBCT)2(μ-dppm)2]Cl4 (2), or [Cd(BBCT)(phosphine)]Cl2 (where phosphine is dppe (3), dppp (4), dppb (5)) and [Cd(BBCT)(amine)]Cl2 (where amine is bipy (6) or phen (7)). The characterizations (molar conductivity, elemental anal., IR spectra and 31P NMR, 1H NMR and 13C NMR spectra) prove that BBCT ligand behaves as a bidentate ligand through the N atom of thiazole ring group and S atom of thion group while the phosphines or amines ligands behave as bidentate ligand through the P atoms or N atoms, resp. Furthermore, the nanostructure of (1) and (7) was examined by SEM and the results demonstrate the presence of regular nanostructures. The complex (1) shows fiber-grip-like geometry with 85-110 nm while complex (7) shows spiny-flowers-like nanostructures with the flower-forming spines within the range of 80-190 nm. The antibacterial activity of the complexes (1, 2, 3, 6, 7) against S.Epidermidis, S. aureus (gram-pos.) and C.Freundii (gram-neg.) was examined using amikacin as a pos. control. However, all the complexes showed a high ability to inhibit the bacterial species studied, and the inhibition zone was better than that obtained with amikacin. Moreover, the anti-cancer activity of the complexes (1) and (7) against ovarian cancer cell was studied and the results show that both complexes gave cell viability values less than 6%.
In addition to the literature in the link below, there is a lot of literature about this compound(1,2-Bis(diphenylphosphino)ethane)Application In Synthesis of 1,2-Bis(diphenylphosphino)ethane, illustrating the importance and wide applicability of this compound(1663-45-2).
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis