Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Inorganic Chemistry Communications called A 2D metal-calixarene aggregate involving in situ generated 5-(4-pyridyl)tetrazolate ligand, Author is Hang, Xinxin; Du, Shangchao; Wang, Shentang; Liao, Wuping, which mentions a compound: 14389-12-9, SMILESS is C1(C2=NN=NN2)=CC=NC=C1, Molecular C6H5N5, Related Products of 14389-12-9.
A novel cobalt-thiacalix[4]arene compound, [Co4Cl2(TC4A)(ptz)2]•H2O (H4TC4A = p-tert-butylthiacalix[4]arene; ptz = 5-(4-pyridyl)tetrazolate) was obtained by solvothermal method, in which ptz was in situ-generated by click reaction of 4-cyanopyridine and sodium azide. This compound is featured with some wavelike layer motifs constructed by bridging the shuttlecock-like Co4-TC4A secondary building units (SBUs) with in situ-generated ptz ligands. Magnetic measurement reveals that the cobalt (II) centers exhibit antiferromagnetic interactions.
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Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis