Category: chiral-nitrogen-ligands

In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Tetrahedral Cu(I) complexes as electrocatalysts for the reduction of protons to dihydrogen gas, published in 2021-07-07, which mentions a compound: 1663-45-2, mainly applied to tetrahedral copper complex preparation electrocatalyst reduction proton dihydrogen preparation; electrochem redox tetrahedral copper complex, SDS of cas: 1663-45-2.

Four copper(I) complexes [Cu(MeCN)4]PF6 (1), [Cu(dppe)2]PF6 (2), [Cu(bpy)2]PF6 (3) and [Cu(bpy)(dppe)]PF6 (4) have been used as electrocatalysts in the generation of dihydrogen from proton reduction Low overpotentials of 0.4 V have been measured using cyclic voltammetry when 1 and 3 were used as the catalysts in the presence of acetic acid as the proton source in acetonitrile. In contrast, a higher overpotential is observed for 4 while 2 is unable to catalyze the process. A mechanism for proton reduction has been proposed.

Here is a brief introduction to this compound(1663-45-2)SDS of cas: 1663-45-2, if you want to know about other compounds related to this compound(1663-45-2), you can read my other articles.

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: 2-Chloro-5-pyridinesulfonyl chloride, is researched, Molecular C5H3Cl2NO2S, CAS is 6684-39-5, about Design and synthesis of novel n-butyphthalide derivatives as promising botanical fungicides.Quality Control of 2-Chloro-5-pyridinesulfonyl chloride.

In order to obtain novel botanical fungicides, three series of novel 6-substituted n-butyphthalide derivatives have been designed and synthesized via nucleophilic addition, reduction, nitrification, amination, sulfonation, Sandmeyer and Suzuki reaction. The mycelium growth rate method was used to evaluate the inhibition activity against eight phytopathogenic fungi in vitro. Preliminary bioassay tests showed that compounds 6f, 6n, 6p, 6r and 7a exhibited better activity for some fungi at 50 μg/mL than the pos. drug hymexazol and lead compound n-butyphthalide (NBP). The preliminary structure-activity relationships indicated that the antifungal activity is significantly affected by the substituents on the benzene ring.

Here is a brief introduction to this compound(6684-39-5)Quality Control of 2-Chloro-5-pyridinesulfonyl chloride, if you want to know about other compounds related to this compound(6684-39-5), you can read my other articles.

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

COA of Formula: C8H7N3O. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: 2-Aminoquinazolin-4(3H)-one, is researched, Molecular C8H7N3O, CAS is 20198-19-0, about Heterocyclic photorearrangements. Some investigations of the photochemical behavior of 3-acylamino-1,2,4-oxadiazoles. Synthesis of the quinazolin-4-one system. Author is Buscemi, Silvestre; Vivona, Nicolo.

Some mechanistic investigations on the photochem. behavior of 1,2,4-oxadiazoles are reported. Irradiation of 3-benzoylamino-5-methyl-1,2,4-oxadiazole at λ = 254 nm in methanol involves excitation of the benzoylamino group chromophore to a triplet state species and induces a 6π electrocyclic closure to a tricyclic intermediate. On the other hand, irradiation of 3-acetylamino-5-phenyl-1,2,4-oxadiazole at λ =254 nm involves excitation of a 5-phenyl-substituted oxadiazole chromophore which leads to the photolysis of the ring O-N bond in a singlet state species. Furthermore, irradiation of some selected 5-Ph substituted oxadiazoles in the presence of a triplet sensitizer produces an excited triplet state species which collapses in a ring closure reaction involving the C5-Ph moiety.

Here is a brief introduction to this compound(20198-19-0)COA of Formula: C8H7N3O, if you want to know about other compounds related to this compound(20198-19-0), you can read my other articles.

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Angewandte Chemie, International Edition called Metal-free Catalytic Olefin Hydrogenation: Low-Temperature H2 Activation by Frustrated Lewis Pairs, Author is Greb, Lutz; Ona-Burgos, Pascual; Schirmer, Birgitta; Grimme, Stefan; Stephan, Douglas W.; Paradies, Jan, which mentions a compound: 3411-48-1, SMILESS is C1=CC2=C(C=C1)C(=CC=C2)P(C1=CC=CC2=C1C=CC=C2)C1=CC=CC2=C1C=CC=C2, Molecular C30H21P, Synthetic Route of C30H21P.

A metal-free catalytic olefin hydrogenation has been demonstrated using a frustrated Lewis pair (FLP) strategy. This development evolved from the recognition that the inability to observe the activation of hydrogen by an FLP at room temperature does not necessary imply the absence of reactivity due to fast equilibrium reaction. In the presence of a substrate, the transient dihydrogen-activation product is intercepted by an olefin, thus effecting hydrogenation. The exptl. findings were confirmed by quantum chem. studies.

If you want to learn more about this compound(Tri(naphthalen-1-yl)phosphine)Synthetic Route of C30H21P, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(3411-48-1).

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 6684-39-5, is researched, Molecular C5H3Cl2NO2S, about Synthesis and biological evaluation of N-(7-indolyl)-3-pyridinesulfonamide derivatives as potent antitumor agents, the main research direction is pyridinesulfonamide indolyl derivative preparation antitumor.Category: chiral-nitrogen-ligands.

The synthesis and antitumor activity of E7070 analogs containing a 3-pyridinesulfonamide moiety is reported. E7070 was selected from our sulfonamide-based compound collections, currently undergoing Phase II clin. trials because of its tolerable toxicity profile and some antitumor responses in the Phase I setting. Of the analogs examined, ER-35745 (I), a 6-amino-3-pyridinesulfonamide derivative, demonstrated significant oral efficacy against the HCT116 human colon carcinoma xenograft in nude mice.

If you want to learn more about this compound(2-Chloro-5-pyridinesulfonyl chloride)Category: chiral-nitrogen-ligands, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(6684-39-5).

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Ollivier, Jean; Dorizon, Philippe; Piras, Pier P.; de Meijere, Armin; Salauen, Jacques researched the compound: Tri(naphthalen-1-yl)phosphine( cas:3411-48-1 ).Recommanded Product: Tri(naphthalen-1-yl)phosphine.They published the article 《Strain, silyl and steric effects on the regioselectivity of palladium(0) catalyzed allyl esters reduction as alternative to the Wittig reaction》 about this compound( cas:3411-48-1 ) in Inorganica Chimica Acta. Keywords: Wittig reaction alternative; olefination reaction; strain effect regioselectivity allyl ester reduction; palladium catalyzed allyl ester reduction; silyl effect regioselectivity allyl ester reduction; steric effect regioselectivity allyl ester reduction. We’ll tell you more about this compound (cas:3411-48-1).

1-(1-Alkenyl)- (I; n =4, R = H, SiMe3, SiEt3, Bu, X = OAc, OCO2Me; n = 1, R = H, SiMe3, Bu, X = OTs) and 1-(1-cycloalkenyl)cycloalkyl esters (acetate, tosylate, mesylate) (II; n = 1, 3, 4; m = 1, 2) underwent palladium(0) catalyzed hydrogenolysis by sodium formate or n-butylzinc chloride as hydride sources. The regioselectivity of the reduction can be monitored either by ring strain, silyl substitution of the allyl moieties or by using the steric effect of trivalent phosphorus ligands related to their cone angles ϑ. Alkylidenecycloalkanes (III) and cycloalkylidenecycloalkanes (IV) have been obtained, generally in good yields, thus providing a convenient alternative to the Wittig olefination and a new access to allylsilanes.

If you want to learn more about this compound(Tri(naphthalen-1-yl)phosphine)Recommanded Product: Tri(naphthalen-1-yl)phosphine, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(3411-48-1).

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

Name: 2-Aminoquinazolin-4(3H)-one. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: 2-Aminoquinazolin-4(3H)-one, is researched, Molecular C8H7N3O, CAS is 20198-19-0, about Derivatives of 4-quinazolone as heat stabilizers for poly(vinyl chloride) and vinyl chloride-vinyl acetate copolymers. Author is Kasymova, S. S.; Masharipov, S. M.; Tadzhieva, Kh. S.; Makhmudov, S. A.; Yun, L. M.; Shakhidoyatov, Kh. M..

The stabilizing effect of 4-quinazolone  [491-36-1], 2-amino-4-quinazolone (I) [20198-19-0], 2-amino-3-methyl-4-quinazolone (II) [91810-61-6] and 2-amino-3-methyl-6-nitro-4-quinazolone  [91810-62-7] on PVC  [9002-86-2] and vinyl acetate-vinyl chloride copolymer  [9003-22-9] was studied. The highest heat resistance of the polymers was obtained by stabilization with I, and to a lower degree, with II, whereas the other quinazolone derivatives had no stabilizing effect on the polymers. The effect of mixtures of II with com. stabilizers Ca stearate or Ba-Cd stearate on the heat resistance of PVC depended nonmonotonically on the component ratio, whereas the effect of mixtures of I and other quinazolone derivatives with com. stabilizers increased with increasing content of the former.

If you want to learn more about this compound(2-Aminoquinazolin-4(3H)-one)Name: 2-Aminoquinazolin-4(3H)-one, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(20198-19-0).

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

Quality Control of 1,5-Dibromopentane. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: 1,5-Dibromopentane, is researched, Molecular C5H10Br2, CAS is 111-24-0, about Accordion-like effect of flexible organic structure-directing agents in the synthesis of ferrierite zeolite. Author is Almeida, Ramon K. S.; Perez-Pariente, Joaquin; Gomez-Hortiguela, Luis.

Ferrierite zeolite was synthesized by a co-structure-directing route using a highly flexible diquaternary ammonium cation (N,N’-bis-triethylpentanediyldiammonium) as a structure directing agent in combination with tetramethylammonium as a small co-structure-directing agent. Strong alterations of the 13C NMR bands of the bulky organic dication upon confinement within the ferrierite framework suggest a change of conformation driven by host-guest interactions. A combination of mol. mechanics and DFT calculations of the theor. 13C NMR chem. shifts allowed to explain the observed differences in the NMR bands of the dication in solution and when hosted in ferrierite: upon confinement, the flexible dication needs to squeeze through the flexible pentyl chain which locates along the 10 MR ferrierite channels in order to host the two bulky tri-Et ammonium groups in adjacent intersections with 8 MR channels. Our work suggests that highly flexible cations, usually considered as less convenient organic structure-directing agents because of low specificity, have the advantage of being able to properly fit with different zeolite cell dimensions through an accordion-like effect by squeezing or stretching their flexible chains.

If you want to learn more about this compound(1,5-Dibromopentane)Quality Control of 1,5-Dibromopentane, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(111-24-0).

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

HPLC of Formula: 20198-19-0. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: 2-Aminoquinazolin-4(3H)-one, is researched, Molecular C8H7N3O, CAS is 20198-19-0, about 2-Aminoquinazolin-4(3H)-one as an Organocatalyst for the Synthesis of Tertiary Amines. Author is Thakur, Maheshwar S.; Nayal, Onkar S.; Upadhyay, Rahul; Kumar, Neeraj; Maurya, Sushil K..

The potential of 2-aminoquinazolin-4(3H)-one as an organocatalyst for the activation of aldehydes via noncovalent interaction for the synthesis of tertiary amines using formic acid as a reducing agent is reported for the first time. The developed protocol demonstrated a dilated substrate scope for aromatic and aliphatic amines with aromatic and aliphatic aldehydes. Furthermore, the current method was also fruitful for the derivatization of ciprofloxacin and its derivative in good to excellent yields.

If you want to learn more about this compound(2-Aminoquinazolin-4(3H)-one)HPLC of Formula: 20198-19-0, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(20198-19-0).

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: 5-(4-Pyridyl)-1H-tetrazole, is researched, Molecular C6H5N5, CAS is 14389-12-9, about Understanding the formation of metal-oxide based inorganic solids: Assessing the influence of tetrazole molecule.Computed Properties of C6H5N5.

The hydrothermal reaction of Cu(II) salt, ammonium heptamolybdate and 4-ptz (5-(4-pyridyl)tetrazole) at different synthetic conditions yields two compounds [Cu(4-Hptz)(Mo2O7)] (1) and [Cu(4-Hptz)2(H2O)3]2[Mo8O26] (2). Both the compounds 1 and 2 were characterized by routine elemental analyses, IR-, thermogravimetric studies and unambiguously characterized by single crystal x-ray crystallog. Compound 1 exhibits a 3-dimensional bimetallic oxide framework, constructed from the tetrazoles and {CuMo2O7} oxide phase. The coordination ability of N atoms in the tetrazole ring makes the ring acting as a template in the formation of {Cu4Mo6O10} rings, made up of [Mo2O7]2- anions and Cu(II) octahedra; the stacking of these {Cu4Mo6O10} rings along crystallog. c axis gave a 3-dimensional bimetallic oxide framework. Compound 2 consists of infinite octamolybdate chains and Cu-tetrazolate complex cation. The formation of oxide phase under hydrothermal conditions is discussed, giving importance of the role of geometry of the tetrazole ring.

There is still a lot of research devoted to this compound(SMILES：C1(C2=NN=NN2)=CC=NC=C1)Computed Properties of C6H5N5, and with the development of science, more effects of this compound(14389-12-9) can be discovered.

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis