126456-43-7, Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 126456-43-7, Name is (1S,2R)-1-Amino-2,3-dihydro-1H-inden-2-ol
Stereoselective [2,3]-Wittig rearrangement of (1S,2R)-1-amino-indan-2-ol derived amide enolates
An efficient, diastereoselective [2,3]-Wittig rearrangement of alpha-allyloxyamide enolates has been developed using (1S,2R)-1-amino-indan-2-ol as a chiral auxiliary. After auxiliary removal, the resultant optically active a-hydroxy acids have been transformed to functionalized amino acid derivatives.
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Reference£º
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis